• Jacquet, L., le Duigou, A. & Kerbrat, O. A systematic literature review on holistic lifecycle assessments as a basis to create a standard in maritime industry. Int J Life Cycle Assess (2024).
  • Josselin, M., Di Cesare N., Castro, M., Colinart, T., Scarpa, F., Le Duigou, A.,  Hygro-thermal coupling on 4D-printed biocomposites as key for meteosensitive shape-changing materials . Virtual and Physical Prototyping (2024).
  • Cheng, P, Peng, Y, Wang, K, Le Duigou, A, Ahzi, S. 3D printing continuous natural fiber reinforced polymer composites: A review. Polym Adv Technol. 2023;e6242. doi:10.1002/pat.6242
  • Fruleux, T., Correa, D., Castro, M., Poppinga, S., Wang, K., Le Duigou, A., Controlling the Water Diffusion Inside Smart 4D-Printed HBC by Functional Channels. Adv. Funct. Mater. 2023, 2310122.
  • Qinyu Li, Antoine Le Duigou, Vijay Kumar Thakur, Liwu Liu, Jinsong Leng, Fabrizio Scarpa, Three-dimensional water diffusion and modelling of flax/shape memory epoxy composites, Composites Part A: Applied Science and Manufacturing, Volume 171, 2023, 107574, ISSN 1359-835X,
  • Shaima Bellil, Delphin Pantaloni, Darshil U. Shah, Antoine Le Duigou, Christophe Baley, Johnny Beaugrand, Alain Bourmaud, Sofiane Guessasma, Prediction of interfacial behaviour of single flax fibre bonded to various matrices by simulation of microdroplet test, Composites Part C: Open Access, Volume 11, 2023, 100351, ISSN 2666-6820,
  • de Kergariou, C., Demoly, F., Perriman, A., Le Duigou, A., Scarpa, F., The Design of 4D-Printed Hygromorphs: State-of-the-Art and Future Challenges. Adv. Funct. Mater. 2023, 33, 2210353.
  • Ping Cheng, Yong Peng, Kui Wang, Antoine Le Duigou, Song Yao, Chao Chen, Quasi-static penetration property of 3D printed woven-like ramie fiber reinforced biocompositesComposite Structures, Volume 303, 2023, 116313, ISSN 0263-8223,
  • Le Duigou, A.; Grabow, M.; Castro, M.; Toumi, R.; Ueda, M.; Matsuzaki, R.; Hirano, Y.; Dirrenberger, J.; Scarpa, F.; D’Elia, R.; Labstie, K.; Lafont, U. Thermomechanical performance of continuous carbon fibre composite materials produced by a modified 3D printer. Heliyon 2023.
  • Charles de Kergariou, Antoine Le Duigou, Adam Perriman, Fabrizio Scarpa, Design space and manufacturing of programmable 4D printed continuous flax fibre polylactic acid composite hygromorphs, Materials & Design, Volume 225, 2023, 111472, ISSN 0264-1275,
  • Ping Cheng, Kui Wang, Antoine Le Duigou, Jiachen Liu, Zhixiang Liu, Yong Peng, Said Ahzi, A novel dual-nozzle 3D printing method for continuous fiber reinforced composite cellular structuresComposites Communications, Volume 37, 2023, 101448, ISSN 2452-2139,
  • Zolfagharian A, Bodaghi M and Le Duigou A (2022) Editorial: 4D printing and 3D printing in robotics, sensors, and actuators manufacturing. Front. Robot. AI 9:1110571. doi: 10.3389/frobt.2022.1110571
  • Ping Cheng, Yong Peng, Shixian Li, Yanni Rao, Antoine Le Duigou, Kui Wang, Said Ahzi, 3D printed continuous fiber reinforced composite lightweight structures: A review and outlookComposites Part B: Engineering, Volume 250, 2023, 110450, ISSN 1359-8368,
  • Qinyu Li, Antoine Le Duigou, Jianglong Guo, Vijay Kumar Thakur, Jonathan Rossiter, Liwu Liu, Jinsong Leng, and Fabrizio Scarpa, Biobased and Programmable Electroadhesive Metasurfaces,  ACS Applied Materials & Interfaces 2022 14 (41), 47198-47208, DOI: 10.1021/acsami.2c10392
  • Cheng Kui and Chen, Xuanzhen and Le Duigou, Antoine and PENG, Yong and Wen, Wei, P. and W. Compressive property and shape memory effect of 3D printed continuous ramie fiber reinforced biocomposite corrugated structures. Smart Mater. Struct. 2022.
  • Charles de Kergariou, Byung Chul Kim, Adam Perriman, Antoine Le Duigou, Sofiane Guessasma, Fabrizio Scarpa, Design of 3D and 4D printed continuous fibre composites via an evolutionary algorithm and voxel-based Finite Elements: Application to natural fibre hygromorphsAdditive Manufacturing, Volume 59, Part A, 2022, 103144, ISSN 2214-8604,
  • T. Thomas Fruleux, Mickaël Castro, David Correa, Kui Wang, Ryosuke Matsuzaki, Antoine Le Duigou, Geometric limitations of 3D printed continuous flax-fiber reinforced biocomposites cellular lattice structures, Composites Part C: Open Access, Volume 9, 2022, 100313, ISSN 2666-6820,
  • Qinyu Li, Rujie Sun, Antoine Le Duigou, Jianglong Guo, Jonathan Rossiter, Liwu Li, Jinsong Leng, Fabrizio Scarpa, Large datasets of water vapor sorption, mass diffusion immersed in water, hygroscopic expansion and mechanical properties of flax fibre/shape memory epoxy hygromorph compositesData in  Brief, Volume 43, 2022, 108367, ISSN 2352-3409,
  • V. Popineau, A. Célino, M. Péron, C. Baley, A. Le Duigou , Understanding the effect of hygroscopic cycling on the internal stress and stiffness of natural fibre biocompositesComposites Part A: Applied Science and Manufacturing, Volume 158, 2022, 106995, ISSN 1359-835X,
  • Thomas Fruleux, Mickaël Castro, Pierre Sauleau, Ryosuke Matsuzaki and Antoine Le Duigou. Matrix stiffness: a key parameter to control hydro-elasticity and morphing of 3D printed biocomposite ?, Composites Part A: Applied Science and Manufacturing, Volume 156, 2022, 106882, ISSN 1359-835X.
  • Q Li, R Sun, A Le Duigou, J Guo, J Rossiter, LLiu, J Leng and F Scarpa. Programmable and reconfigurable hygro-thermo morphing materials with multifunctional shape transformation, Applied Material Today, Volume 27, 2022, 101414, ISSN 2352-9407,
  • C De Kergariou, H Saidani-Scott, A Perriman, F Scarpa and A Le Duigou. The influence of the humidity on the mechanical properties of 3D printed continuous flax fibre reinforced poly(lactic acid) composites, Composites Part A: Applied Science and Manufacturing, Volume 155, 2022, 106805, ISSN 1359-835X,
  • A. Le Duigou, G. Chabaud, M. Castro, Impression 3D/4D de matériaux composites thermoplastiques, Les Techniques de l’Ingénieur, 2021, doi:10.51257/a-v1-bm7922.
  • A. Le Duigou, T Fruleux, R. Matsuzaki, G. Chabaud, M. Ueda, M. Castro, 4D printing of continuous flax-fibre based shape-changing hygromorph biocomposites: Towards sustainable metamaterials, Materials & Design,Volume 211, 2021, 110158, ISSN 0264-1275,
  • M. Spahic, N. Di Cesare, A. Le Duigou, V. Keryvin, Multi-scale analysis of the flexural behaviour of 3D printed cellular polymer materials: Comparison between morphing and sandwich beams, Composite Structures, Volume 273, 2021, 114249, ISSN 0263-8223,
  • Popineau, V., Célino, A., Le Gall, M. et al. Vacuum-Bag-Only (VBO) Molding of Flax Fiber-reinforced Thermoplastic Composites for Naval Shipyards. Appl Compos Mater 28, 791–808 (2021).
  • Samuel Réquilé, Brahim Mazian, Marie Grégoire, Salvatore Musio, Maxime Gautreau, Lucile Nuez, Arnaud Day, Pascal Thiébeau, Florian Philippe, Brigitte Chabbert, Anne Chamussy, Darshil U. Shah, Johnny Beaugrand, Vincent Placet, Jean-Charles Benezet, Antoine le Duigou, Mahadev Bar, Luc Malhautier, Emmanuel De Luycker, Stefano Amaducci, Christophe Baley, Anne Bergeret, Alain Bourmaud, Pierre Ouagne, Exploring the dew retting feasibility of hemp in very contrasting European environments: Influence on the tensile mechanical properties of fibres and composites, Industrial Crops and Products, Volume 164, 2021, 113337, ISSN 0926-6690,

43 A. Le Duigou, A Boumaud, P Davies and C Baley, Long term in natural seawater of flax/PLA biocomposites, Ocean engineering, 90, 140-148, 2014

44 M Deroiné, A Le Duigou, YM Corre, PY Le Gac, P Davies, G Cesar, S Bruzaud, Accelerated ageing and lifetime prediction of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in distilled water, Polymer testing, 2014, 39, 70-78

45 A Le Duigou and C Baley. Coupled Micromechanical Analysis and Life Cycle Assessment as an Integrated Tool for Natural Fibre Composites Development, Journal of Cleaner Production. 2014, 83, 63-69

46 A Le Duigou, Y Grohens, C Baley, R Creachcadec, P Davies, L Sohier. A multi-scale study of the interface between natural fibres and a biopolymer, Composites Part A.65, 2014, 161-168

47 Le Duigou, A, Kervoelen A, Le Grand A, Nardin M and Baley C. Interfacial properties of flax fibre-epoxy resin systems : existence of a complex interphase, Composite Science and Technology, 2014, 100, 152-157

48 Gourier C, Le Duigou A, Bourmaud A, Baley C. Mechanical analysis of elementary flax fibre tensile properties after different thermal cycles, Comp Part A, 2014, 64, 159-166

49 Deroiné, M, Le Duigou A, Corre YM, Davies P, Cesar G, Bruzaud, S. Seawater accelerated ageing of poly(3-hydroxybutyrate-co-3- hydroxyvalerate), Polymer Degradation and stability, 2014, 105, 237-247

50 Deroiné, M, Le Duigou A, Corre YM, Davies P, Cesar G, Bruzaud, S. Accelerated ageing of polylactide in aqueous environments: Comparative study between distilled water and seawater, Polymer Degradation and stability, 2014, 39, 70-78

51 Coroller G, Lefeuvre A, Le Duigou A, Bourmaud A, Ausias G, Gaudry T, Baley C. Effect of flax fibres individualisation on tensile failure of flax/epoxy unidirectional composite, Composite Part A, 2013 Accepted

52 Le Duigou A, Davies P and C.Baley, Exploring durability of interfaces in flax fibre/epoxy micro-composites, Composite Part A, 2013, 48, 121-128

53 Baley C, Le Duigou A, Davies P, Bourmaud, A, Influence of drying on the mechanical behaviour of flax fibres and their unidirectional composites. Composite Part A , 2012, 43(8) 26-33

54 Le Duigou A, Bourmaud A, Balnois E, Davies P, Baley C. Improving the interfacial properties between flax fibres and PLLA by a water fibre treatment and drying cycle, Industrial Crop and Product, 2012, 39, 31-39

55 Le Duigou A, Davies P and C.Baley. Substitution of glass/polyester composites by Flax/PLLA biocomposites. Is is justified ? Journal of biobased material and bioenergy. 2011, 5 , 466-482

56 Le Duigou A., Deux JM, Davies P, Baley C. PLLA/flax mat/balsa bio-sandwich Environmental Impact and Simplified Life Cycle Analysis manufacture and mechanical properties. App Comp Mat. 2011, 1-16

57 Le Duigou A, Deux JM, Davies P et C.Baley. Protection of flax/PLLA biocomposites from seawater ageing by external layers of PLLA, International journal of Polymer Science, 2011, 1-9

58 Bourmaud A., Le Duigou A., Baley C., What’s the technical and environmental interest to reuse a recycled poly(propylene)-hemp fiber composites ?, Polymer Degradation and Stability, 2011, 96 (10), 1732-1739

59 Le Duigou, A. Davies, P. and C Baley, Environmental impact analysis of the production of flax fibres to be used as composite material reinforcement”, Journal of Biobased material and bioenergy, 5, 1-13, 2011

60 Le Duigou A., Deux JM, Davies P, Baley C. PLLA/flax mat/balsa bio-sandwich manufacture and mechanical properties. Applied Composite Material. 1-18, 2010

61 Le Duigou A. Davies P. Baley C. Macroscopic analysis of interfacial properties of flax/PLLA biocomposites. Composites Science and technology, 70(11),2010, 1612-1620

62 Le Duigou A., P. Davies, C.Baley. Interfacial bonding of flax/Poly(L-lactide) bio-composites. Composites Science and Technology.2010, 70,2,231-239

63 Bourmaud, J.Rivière, G.Raj, A. Le Duigou, C.Baley. Investigation of the use of a mussel-inspired compatibilizer to improve the matrix-fiber adhesion of a biocomposite, Polymer testing, 28(6), 2009, 668-672.

64 Le Duigou A., Davies P, Baley C. Seawater aging flax/PLLA composites. Polymer Degradation and Stability, 94(7),2009,1151-1162

65 Le Duigou, I. Pillin, A. Bourmaud, P. Davies, C. Baley Effect of recycling on mechanical behaviour of bio-compostable flax/poly(L-lactide) composites, Composites Part A, 39(9), 2008, 1471-1478

-2020 « Materials inspired by pine cone», French regional scientific journal Sciences ouest January

-2019 Video :  Nature = Futur « Meteosensitive like pine cone», la belle société production,, ordered by  French government

-2019 Chapter n°15 in Biomimétisme  de Jean-Philippe Camborde, éd. Quæ, 2019

-2018 Publication in JEC Magazine for hygromorph biocomposites

-2017 Invited by CEEBIOS (European center on biomimicry) for hygromorph biocomposites

-2017 Selection of my work by CNRS/RATP for a poster campaign in Paris Montparnasse station:  “bioinspired hygromorph biocomposites inspired by pine cone seeds dispersal”